{"id":153,"date":"2021-06-21T15:12:36","date_gmt":"2021-06-21T15:12:36","guid":{"rendered":"https:\/\/rodionovlab.org\/?page_id=153"},"modified":"2023-03-21T18:06:03","modified_gmt":"2023-03-21T18:06:03","slug":"publications","status":"publish","type":"page","link":"https:\/\/rodionovlab.org\/?page_id=153","title":{"rendered":"Publications"},"content":{"rendered":"\n

PhD and Postdoctoral Career:<\/strong><\/h2>\n\n\n\n

1.<\/strong>       “Mechanism of the Ligand-Free Cu(I)-Catalyzed Azide-Alkyne Cycloaddition Reaction” Rodionov, V.O.; Fokin, V.V.; Finn, M.G. Angew. Chem. Int. Ed.<\/em> 2005, 44<\/strong>, 2210-2215.<\/p>\n\n\n\n

This work has been featured on the cover of Angewandte Chemie<\/em> and highlighted in Chemical & Engineering News<\/em>, Feb. 21, 2005, p. 36.<\/p>\n\n\n\n

2.<\/strong>       “Benzimidazole and Related Ligands for Cu-Catalyzed Azide-Alkyne Cycloaddition” Rodionov, V.O.; Presolski, S.I.; Gardinier, S.; Lim, Y.-H.; Finn, M.G. J. Am. Chem. Soc.<\/em> 2007, 129<\/strong>, 12696-12704.<\/p>\n\n\n\n

3.<\/strong>       “Ligand-Accelerated Cu-Catalyzed Azide-Alkyne Cycloaddition: a Mechanistic Report” Rodionov, V.O.; Presolski, S.I.; Diaz D.D.; Fokin, V.V.; Finn, M.G. J. Am. Chem. Soc.<\/em> 2007, 129<\/strong>, 12705-12712.<\/p>\n\n\n\n

4.<\/strong>       “Transition-Metal-Free Catalytic Synthesis of 1,5-Diaryl-1,2,3-triazoles” Kwok, S.W.; Fotsing, J.R.; Fraser, R.J.; Rodionov, V.O.; Fokin, V.V. Org. Lett.<\/em> 2010, 12<\/strong>, 4217\u20134219.<\/p>\n\n\n\n

5.<\/strong>       “Easy Access to a Family of Polymer Catalysts from Modular Star Polymers” Rodionov, V.O.; Gao, H.; Scroggins, S.; Unruh, D.A.; Avestro, A.J.; Fr\u00e9chet J.M.J. J. Am. Chem. Soc.<\/em> 2010, 132<\/strong>, 2570\u20132572.<\/p>\n\n\n\n

Independent Research<\/strong>:<\/h2>\n\n\n\n

<\/p>\n\n\n\n

  1. “Arm-first synthesis of hyperbranched-core star polymers via<\/em> copper-catalyzed azide-alkyne cycloaddition” K.M. Fuller, D. Clay, S.R. Almahdali, A. Paterson, C.M. Barratt, V.G.Desyatkin, V.O. Rodionov European Polymer Journal<\/em> 2023, 111987, DOI: 10.1016\/j.eurpolymj.2023.111987.<\/li>
  2. “Synthesis and conformational studies of hyperbranched-core star polymers with poly(\u03b3-benzyl-l-glutamate) arms” C.M. Barratt, T.K. Haraniya, S.J. Iwamasa, J.J. Yun, V.G. Desyatkin, K.G. Wilcox, S.A. Morozova, V.O. Rodionov European Polymer Journal<\/em> 2023 186, 111859, DOI: 10.1016\/j.eurpolymj.2023.111859.<\/li>
  3. “Scalable Synthesis and Characterization of Multilayer \u03b3-Graphyne, New Carbon Crystals with a Small Direct Band Gap” V.G. Desyatkin, W.B. Martin, Aliev A.E. N.E. Chapman, A.F. Fonseca, D.S. Galv\u00e3o, E.R. Miller, K.H. Stone, Z. Wang, D. Zakhidov, F.T. Limpoco, S.R Almahdali, S.M. Parker, R.H. Baughman, V.O. Rodionov J. Am. Chem. Soc.<\/em> 2022 144 (39), 17999-18008 DOI: 10.1021\/jacs.2c06583<\/li>
  4. \u201cUpdate: An Efficient Synthesis of Poly(ethylene glycol)- Supported Iron(II) Porphyrin Using a Click Reaction and its Application for the Catalytic Olefination of Aldehydes\u201d Chinnusamy T.; Rodionov V.O.; K\u00fchn F.E.; and Reiser O. Adv. Synth. Catal.<\/em> 2012, 354<\/strong>, 1827\u20131831 <\/li>
  5. \u201cSequence-Controlled Copolymers of 2,3,4,5,6-Pentafluorostyrene: A Mechanistic Insight and Application to Organocatalysis\u201d O\u2019Shea J.-P.; Solovyeva V.; Guo X.; Zhao J.; Hadjichristidis N.; and Rodionov V.O. Polym. Chem.<\/em> 2014, 5<\/strong>, 698-701 <\/li>
  6. \u201cSequence-Controlled Copolymers of 2,3,4,5,6-Pentafluorostyrene: A Mechanistic Insight and Application to Organocatalysis\u201d O\u2019Shea J.-P.; Solovyeva V.; Guo X.; Zhao J.; Hadjichristidis N.; and Rodionov V.O. Polym. Chem.<\/em> 2014, 5<\/strong>, 698-701 <\/li>
  7. \u201cStar Block-Copolymers: Enzyme-Inspired Catalysts for Oxidation of Alcohols in Water\u201d Mugemana C.; Chen B.-T.; Bukhryakov K.V.; and Rodionov V.O. Chem. Comm.<\/em> 2014, 50<\/strong>, 7862-7865 <\/li>
  8. \u201cOne-Pot Synthesis of Au@SiO2<\/sub> Catalysts: A Click Chemistry Approach\u201d Solovyeva V.A.; Vu K.B.; Merican Z.; Sougrat R.; and Rodionov V.O. ACS Comb. Sci.<\/em> 2014, 16<\/strong>, 513-517. This work has been featured on the cover of ACS Comb. Sci.<\/em> (October 2014) <\/li>
  9. \u201cNanocapsules with Fluorous Filling: A \u201cMolecular Zipper\u201d Approach\u201d Merican Z.; Mugemana C.; Almahdali S.; Vu K.B.; O\u2019Shea J.-P.; Sougrat R.; and Rodionov V.O. J. Polym. Sci. A: Polym. Chem.<\/em> 2015, 53<\/strong>, 215-218 <\/li>
  10. \u201cPerfluorinated Cobalt Phthalocyanine Effectively Catalyzes Water Electrooxidation\u201d Morlan\u00e9s N.; Joya K.S.; Takanabe K.; and Rodionov V.O. Eur. J. Inorg. Chem,<\/em> 2015, 1<\/strong>, 49-52. <\/li>
  11. \u201cCooperative Catalysis with Block-Copolymer Micelles: a Combinatorial Approach\u201d Bukhryakov K.V.; Desyatkin V.G.; O\u2019Shea J.-P.; Almahdali S.; Solovyeva V.; and Rodionov V.O. ACS Comb. Sci.<\/em> 2015, 17<\/strong>(2), 76-80. This work has been highlighted in Chemical & Engineering News<\/em>, Jan. 19, 2015, p. 24. <\/li>
  12. \u201cEnzyme-inspired Functional Surfactant for Aerobic Oxidation of Activated Alcohols to Aldehydes in Water\u201d Chen B.-T.; Bukhryakov K.V.; Sougrat R.; and Rodionov V.O. ACS Catalysis<\/em> 2015, 5<\/strong>(2), 1313\u20131317. <\/li>
  13. \u201cSurface-Bound Ligands Modulate Chemoselectivity and Activity of a Bimetallic Nanoparticle Catalyst\u201d Vu K.B.; Bukhryakov K.V.; Anjum D.H.; and Rodionov V.O. ACS Catalysis<\/em> 2015, 5<\/strong>(4), 2529\u20132533. <\/li>
  14. \u201cAmplification of Chirality through Self-Replication of Micellar Aggregates in Water\u201d Bukhryakov K.V.; Almahdali S.; and Rodionov V.O. Langmuir.<\/em> 2015, 31<\/strong>(10), 2931\u20132935 <\/li>
  15. \u201cImmobilization of Molecular Cobalt Electrocatalyst by Hydrophobic Interaction with Hematite Photoanode for Highly Stable Oxygen Evolution\u201d Joya K.S.; Morlan\u00e9s N.; Maloney E.; Rodionov V.O.; and Takanabe K. Chem. Comm.<\/em> 2015, 51<\/strong>, 13481-13484 <\/li>
  16. \u201cPalladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer\u201d Bukhryakov K.V.; Mugemana C.; Vu K.B.; and Rodionov V.O. Org. Lett.<\/em> 2015, 17<\/strong> (19), 4826\u20134829 <\/li>
  17. Mining chemical activity status from high-throughput screening assays\u201d Othman S.; Ba-alawi W.; Afeef M.; Essack M.; Rodionov V.; Kalnis P.; and Bajic V.B. PLoS One<\/em> 2015; doi:10.1371\/journal.pone.0144426 <\/li>
  18. \u201cSimultaneous Reduction of CO2<\/sub> and Splitting of H2<\/sub>O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst\u201d Morlan\u00e9s N.; Takanabe K.; and Rodionov V.O. ACS Catalysis<\/em> 2016, 6<\/strong>, 3092\u20133095 <\/li>
  19. \u201cRing opening metathesis polymerization of cyclopentene using a ruthenium catalyst confined by a branched polymer architecture\u201d Mugemana C.; Bukhryakov K.V.; Bertrand O.; Vu K.B.; Gohy J.-F.; Hadjichristidis N.; and Rodionov V.O. Polym. Chem.<\/em> 2016, 7<\/strong>, 2923\u20132928. This work has been featured on the cover of Polym. Chem.<\/em> (April 2016) <\/li>
  20. \u201cCooperative Organocatalysis of Mukaiyama-Type Aldol Reactions by Thioureas and Nitro Compounds\u201d Bukhryakov K.V.; Desyatkin V.; and Rodionov V.O. Chem. Comm.<\/em> 2016, 52<\/strong>, 7576\u20137579 <\/li>
  21. \u201cControllable Catalysis with Nanoparticles: Bimetallic Alloy Systems and Surface Adsorbates\u201d Chen T. and Rodionov V.O. ACS Catalysis<\/em> 2016, 6<\/strong>, 4025\u20134033 <\/li>
  22. \u201cAn Efficient and Stable Hydrophobic Molecular Cobalt Catalyst for Water Electrooxidation at Neutral pH\u201d Chen B.-T.; Morlan\u00e9s N.; Adogla E.; Takanabe K.; and Rodionov V.O. ACS Catalysis<\/em> 2016, 7<\/strong>, 4647\u20134652 <\/li>
  23. \u201cHollow Nanospheres with Fluorous Interiors for Transport of Molecular Oxygen in Water\u201d Vu K.B.; Almahdali S.; Bukhryakov K.V.; and Rodionov V.O. ChemistrySelect<\/em> 2016, 1<\/strong>(12), 3306-3309, DOI:10.1002\/slct.201600602 <\/li>
  24. \u201cPolystyrene-supported Cu(II)-R-Box as recyclable catalyst in asymmetric Friedel-Crafts reaction\u201d Desyatkin V.G.; Anokhin M.V.; Rodionov V.O.; and Beletskaya I.P. Russ. J. Org. Chem.<\/em> 2016, 52<\/strong>(12), 1717-1727 <\/li>
  25. \u201cpH-Sensitive Amphiphilic Block-Copolymers for Transport and Controlled Release of Oxygen\u201d Patil Y.; Almahdali S.; Vu K.B.; Zapsas G.; Hadjichristidis N.; and Rodionov V.O. Polym. Chem.<\/em> 2017, 8<\/strong>, 4322-4326 This work has been featured on the cover of Polym. Chem.<\/em> (August 2017) <\/li>
  26. \u201cThiols Make for Better Catalysts: Au Nanoparticles Supported on Functional SBA-15 for Catalysis of Ullmann-type Homocouplings\u201d Chen T.; Chen B.-T.; Bukhryakov K.V.; and Rodionov V.O. Chem. Comm.<\/em> 2017, 53<\/strong>, 11638-11641. This work has been featured on the cover of Chem. Comm.<\/em> (October 2017) <\/li>
  27. \u201cA Novel Poly(vinylidene fluoride)-Based 4-Miktoarm Star Terpolymer: Synthesis and Self-Assembly\u201d Patil Y.; Bilalis P.; Polymeropoulos G.; Almahdali S.; Hadjichristidis N.; and Rodionov V.O. Mol. Pharmaceutics.<\/em> 2018, 15<\/strong>, 3005-3009<\/li><\/ol>\n\n\n\n

    Book Chapters<\/strong>:<\/h2>\n\n\n\n
    • Mugemana C.; Almahdali S.; and Rodionov, V. O. \u201cSequence-Controlled Polymerization Guided by Aryl-Fluoroaryl \u03c0-Stacking.\u201d in Sequence-Controlled Polymers: Synthesis, Self-Assembly, and Properties<\/em> (ACS Symposium Series)<\/em>, pp. 235-253, DOI: 10.1021\/bk-2014-1170.ch016<\/li><\/ul>\n\n\n\n

      Patents and Patent Applications<\/strong>:<\/h2>\n\n\n\n
      1. Finn, M. G.; Rodionov, V. O. \u201cPreparation of ligands for copper-catalyzed azide-alkyne cycloaddition reactions.\u201d US 20100197871 A1, 2009<\/strong>, 55pp.<\/li>
      2. Rodionov, V.O.; Khanh, V.B. \u201cSurface functionalized hollow silica particles and composites\u201d WO 2017\/085544 A1, 2017<\/strong>, 38pp.<\/li><\/ol>\n","protected":false},"excerpt":{"rendered":"

        PhD and Postdoctoral Career: 1.       “Mechanism of the Ligand-Free Cu(I)-Catalyzed Azide-Alkyne Cycloaddition Reaction” Rodionov, V.O.; Fokin, V.V.; Finn, M.G. Angew. Chem. Int. Ed. 2005, 44, 2210-2215. This work has been featured on the cover of Angewandte Chemie and highlighted in Chemical & Engineering News, Feb. 21, 2005, p. 36. 2.       “Benzimidazole and Related Ligands for […]<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/rodionovlab.org\/index.php?rest_route=\/wp\/v2\/pages\/153"}],"collection":[{"href":"https:\/\/rodionovlab.org\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/rodionovlab.org\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/rodionovlab.org\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/rodionovlab.org\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=153"}],"version-history":[{"count":18,"href":"https:\/\/rodionovlab.org\/index.php?rest_route=\/wp\/v2\/pages\/153\/revisions"}],"predecessor-version":[{"id":205,"href":"https:\/\/rodionovlab.org\/index.php?rest_route=\/wp\/v2\/pages\/153\/revisions\/205"}],"wp:attachment":[{"href":"https:\/\/rodionovlab.org\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=153"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}